In What Episode in the anime does Lufffy meet Boa Hancock? | Yahoo Answers
No, it's actually episode "The Secret Hidden on the Backs – Luffy and the Snake Princess Meet. Luffy meets Hancock when he is transported to Amazon Lily by Kuma following the events of Sabaody Archipelago Arc. The Fisherman Island. She was first mentioned by the Risky Brothers at the end of the Thriller Bark Arc when Before Hancock fell in love with Luffy and when she is not around Luffy, her eyes tend . Whenever he is in her presence, she is quick to turn shy, barely able to meet him in 12) and Episode , Hancock revealed as a Kuja pirate.
Margaret is Turned to Stone!! Hancock tries, but fails to turn him to stone with her powers when he mistakes her Love-Love abilities for Foxy's Slow-Slow Beam. Luffy tries to escape but gets captured by the Kuja pirates and is brought to the execution arena.
Margaret confesses to bringing him to the island, and Hancock turns her and two of her companions to stone. Enraged at the Kuja's lack of empathy for Margaret, Luffy punches out Bakula, the panther sent to execute him. Hancock's two younger sisters, Sandersonia and Marigold, jump into the arena and using their Devil Fruit powers, transform into snake-women to fight Luffy.
The Snake Sisters' Haki Power!! Hebi Shimai no Haki no Chikara!! When Sandersonia plans on breaking the petrified Marguerite in order to cause Luffy pain, he screams for her to stop, forcing her to stop and causing many of the assembled warriors to faint by using a special and rare kind of Haki Hancock identifies as a Conqueror's Spirit.
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With Margaret safe, Luffy prepares to fight at full power. Desperate to finish him off, Marigold and Sandersonia attempt to finish him off with their strongest moves, but Luffy fights them off and ties their tails together.
Marigold's fire attack accidentally burns the clothes off Sandersonia's back, prompting Hancock to order everyone to evacuate or risk seeing the "Gorgon Eyes". Luffy covers the symbol on her back with his body, saying that while she is his enemy, her secret has nothing to do with his fight. Boa Hancock is then moved to tears. Luffy is brought to the palace, where Hancock is shocked to learn of Luffy's attack on the World Noble. Luffy learns that the three sisters were once slaves of the World Nobles, but were freed when Fisher Tiger attacked Mariejois, and that he eventually founded the Sunny Pirates from former slaves.
Hancock then grants Luffy use of her ship. When Luffy hears that they are planning on executing his brother Ace at Marinford to lure Whitebeard out, he decides to save him from the prison Impel Down before he's transported away.
The only hope of him getting there in time is for Hancock to answer to the call for the Warlords so Luffy can hitch a ride on her ship, but the empress has just caught a disease, and is lying in bed. Hancock Madly in Love! Luffy requests that Hancock take him to Impel Down, and when Hancock agrees, much to everyone's shock, Nyon realizes that she is in love with Luffy. Hancock boards Momonga's ship to answer the summons, smuggling Luffy aboard inside her clothes, and de-petrifies the crew before the ship sails to Impel Down.
Elsewhere, Sengoku notes that Jimbei, one of the Seven Warlords, refuses to fight and is being held in Impel Down, and learns that the 23 ships observing Whitebeard's flagship have been destroyed.
Garp visits Ace in prison. Nami finds herself on Weatheria, a sky island dedicated to the study of weather, and learns about a special rope that can create winds.
She uses the rope with her Clima Tact to stop a storm. Franky ends up on the futuristic Mechanical Island, and is frozen solid in the cold. He is rescued but because there is no cola on the island, is given tea instead and becomes a gentleman.
While searching for food to regain his strength, some residents of the island capture him. Boa Sandersonia caught Luffy using her tail and Luffy wondered why his attacks hurt even when he fought against Sentomaruit was the same feeling he got. Luffy also acknowledged that they were Devil Fruit users and asked why they lied about being cursed. She told him it was a secret that cannot be told to anyone even if the person is about to die.
She stated that he is unable to use Haki, saying that people not from their island are unfamiliar with it. She predicted Luffy's attack and dodged, then followed by attacking him using the Snake Slam. Boa Marigold then attacked him using the Snake Stick.
List of One Piece episodes (season 12) - Wikipedia
Both sisters attacked him and Luffy fell backwards more trying not to hit the statues, and towards into the spikes. Luffy missed falling into the spikes by anchoring his hands and legs. Boa Hancock commented that Luffy was all talk and a silly man, in which Luffy retorted by telling her to shut it and called her an idiot.
The crowd got very angry at Luffy's insult of Hancock and called for his immediate execution. Hancock then ordered her sisters to kill Luffy right away. Sandersonia then picked up Marguerite's statue and threatened to break it saying, because she saved Luffy's life as he had stated. Marigold indicated to Luffy that the ordeal is a public execution and not a fight as he thinks it is. Sandersonia prepared to execute Marguerite even with Luffy's yelling for her to stop.
As she counted down to smash the statue, Luffy yelled out "I told you to stop, dammit" causing him to unleash his Haoshoku Haki. This surprised many in the crowd who could withstand it and rendered others unconscious. Kikyoand the Boa sisters were amazed as they realized what type of power Luffy had just unleashed.